Q.

Formation of NO2F from NO2and F2 as per the reaction 2NO2(g)+F2(g)2NO2F(g) is a second order reaction, first order with respect to NO2 and first order with respect to F2. If NO2 and F2 are present in a closed vessel in ratio 2 : 1 maintained at a constant temperature with an initial total pressure of 3 atm, what will be the total pressure in the vessel after the reaction is complete?

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a

1 atm

b

2.5 atm

c

3 atm

d

2 atm

answer is B.

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Detailed Solution

In the reaction we have,

2NO2+F22NO2F   2           1           -   0            0            2

Here two atm of nitrogen dioxide used 1 atm of florine. It will create 2 atm of reactant is formed.

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