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Q.

For NH4HS(s)NH3(g)+H2S(g) the observed pressure for reaction mixture in equilibrium is 1.12 atm at 106°c. The value of K, for the reaction is:

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a

31.36 atm2

b

3 .136 atm2

c

6 .98 atm2

d

0 .3136 atm2

answer is B.

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Detailed Solution

NH4HS(s) Pressure at equilibrium NH3(g)P+H2S(g)P
 Total pressure at equilibrium = 2p = 1. 12 atm
P = 1.12/2 atm
 Kp=PNH3×PH2S
Kp=1.122×1.122=0.3136atm2

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