Q.

For SO2Cl2(g)SO2(g)+Cl2(g), Pressure of SO2Cl2 changed from 5 atm to 4 atm in 10 min. Then, pressure of SO2Cl2 at the end of 30 minutes will be (in atm) 

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a

5.56

b

2.56

c

3.56

d

4.56

answer is A.

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Detailed Solution

SO2Cl2(g)SO2(g)+Cl2(g) is a first order reaction 

For any first order reaction rate constants are same

k=2.303tlogp0p

2.30310log54=2.30330log5p

p = 2.56 atm

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