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Q.

Four complexes are given :

(P) CoClNH352+ (Q) CoNH35H2O3+

(R) CoNH363+ (S) Co(CN)63

All of them exhibit at least one of the following 4 colours viz, violet, red, yellow orange, pale yellow. One of them absorbs light in the U.V. region. Choose the correct statement(s).

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a

Order of wavelength of light absorbed: P > Q > R > S

b

S must be violet in colour

c

R must have absorbed wavelength of blue colour light

d

Q must be pale yellow in colour

answer is A, C.

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Detailed Solution

Here,

Order of Δ0:(S)>(R)>(Q)>(P);Δ01λabs

Question Image

Order of λabs:

SU.V.< RBlue< QGreen < PYellow 

Colour transmitted Pale Yellow, yellow orange, Red, Violet respectively.

Thus, A and C are correct.

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