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Q.

Four containers are taken at the same temperature, as shown in the figure :

Question Image

 

 

 

 

 

 

 

(a) 500 mL of  10%(/W) urea solution

(b) 500 mL of  10%(w/w) urea solution

(c) 400 mL of 10%(w/w) urea solution

(d) 500 mL of 20%(w/w) urea solution

The correct order of vapour pressure of these solution is:

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a

PC<PA<PB<PD

b

PD<PC<PA<PB

c

PC<PA=PB=PD

d

PA=PB=PC<PD

answer is C.

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Detailed Solution

Vapor pressure is same as the concentration of the solution are same. 

In a, b, and d the concentration is same thus, they will have the same vapor pressure. Solution c has the lowest vapor pressure will less solution.

Thus, the correct order of vapor pressure,

PA=PB=PC<PD

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