Four different identical vessels at same temperature contains one mole each of  ${\mathrm{C}}_2{\mathrm{H}}_6,{\mathrm{CO}}_2$

${\mathrm{Cl}}_2$ and ${\mathrm{H}}_2\mathrm{S}$ at pressure $P_1,P_2,P_3$ and $P_4$ respectively. The value of van der Waal's constant ' a ' for ${\mathrm{C}}_2{\mathrm{H}}_6,{\mathrm{CO}}_2,{\mathrm{Cl}}_2$ and ${\mathrm{H}}_2\mathrm{S}$ is 5.562, 3.640, ${\mathrm{L}}^2$ and ${\mathrm{mol}}^{-2}$ respectively. Then :