Q.

Four grams of hydrocarbon CxHy on complete combustion gave 12 grams of CO2. What is the empirical formula of the hydrocarbon?

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a

C4H9

b

CH3

c

CH

d

C3H8

 

answer is D.

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Detailed Solution

CxHy + (x+y/4) O2  xCO2 + y/2H2O

1 mole of CxHy gives x moles of CO2

given, 412x+ymoles of CxHy gives 1244moles of 

4x/ 12x + y = 12/ 44

or, 8x = 3y

x/ y = 3/ 8

Hence, the empirical formula is CH8 3 .

Thus, the correct option is D.

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