Q.

Four grams of hydrocarbon (CxHy) on complete combustion gave 12grams of CO2. What is the empirical formula of the hydrocarbon ? (C = 12 ; H = 1)

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a

CH

b

CH3

c

C4H9

d

C3H8

answer is D.

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Detailed Solution

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Weight of CxHy = 4 gm

Weight of CO2 = 12 gm

% of carbon = 1244×WtCO2WO.C×100 =1244×124×100 = 81.8 %

% of Hydrogen  =  18.2%

 

 CH
Mass ratio81.818.2
Gram atom ratio81.81218.21
Gram atom ratio6.8218.2
Gram atom ratio6.826.8218.26.82
Gram atom ratio1×32.67×3
 38

E.F of the compound is = C3 H8

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