Four set of values of quantum numbers (n, L, m and s) are given below. The values does not provide a permissible solution of wave equation is  $3,3,1,-\frac{1}{2}$

As is well known, quantum no's values are
$\mathrm{n}=1,2,3...$
$\mathrm{I}=0$ to $(\mathrm{n}-1)=0, 1, 2..$
$\mathrm{m}=-\mathrm{l}$to $+\mathrm{l}$
$s=1/2$ and $-1/2$
$3,3,1,-\frac{1}{2}$ is not possible as $\mathrm{n}=\mathrm{l}$,

this cannot be done.