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Q.

Four successive members of the first row transition elements are listed below with atomic numbers. Which one of them is expected to have the highest EM3+/M+20 value

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a

Cr(Z=24)

b

Mn(Z=25)

c

Fe(Z=26)

d

Co(Z=27)

answer is D.

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Detailed Solution

ECr3+/Cr2+0=0.41V;EMn3+/Mn2+0=+1.57V;EFe3+/Fe2+0=+0.77V;ECo3+/Co2+0=+1.97V SRP value 

normally increases from left to right in the period of d block elements. Some SRP value are exceptionally higher due to stability of product ion. For e.g. 

EMn3+/Mn2+0=+1.57V; ECo3+/Co2+0=+1.97V.

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