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Q.

From the following data, mark the option(s) where ΔH is correctly written for the     given reaction.

Given: H+aq+OHaqH2Ol;ΔH=57.3kJ

                                                ΔHsolutionofHAg=70.7kJ/mol

                                                ΔHsolutionofBOHg=20kJ/mol

            ΔHionizationofHA=15kJ/mol  and  BOH  is a strong base

 ReactionΔrHkJ/mol
A)HAaq+BOHaqBAaq+H2O - 42.3
B)HAg+BOHgBAaq+H2O-93
C)HAgH+aq+Aaq- 55.7   
D)B+aq+OHaqBOHaq-20

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a

2

b

1

c

3

d

4

answer is A, B, C.

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Detailed Solution

a) ΔH=15+057.3=42.3kJ

b) HA+BOHBA+H2O

c) ΔH=70.7+15=55.7

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From the following data, mark the option(s) where ΔH is correctly written for the     given reaction.Given: H+aq+OH−aq→H2Ol; ΔH=−57.3kJ                                                ΔHsolution of HAg=−70.7 kJ/mol                                                ΔHsolution of BOHg=20 kJ/mol            ΔHionization of HA=15 kJ/mol  and  BOH  is a strong base ReactionΔrHkJ/molA)HAaq+BOHaq→BAaq+H2O - 42.3B)HAg+BOHg→BAaq+H2O-93C)HAg→H+aq+A−aq- 55.7   D)B+aq+OH−aq→BOHaq-20