Q.

From the following half-cell reactions and their potentials, what is the smallest possible standard e.m.f. for spontaneous reactions?
PO43(aq)+2H2O(l)+2eHPO32+3OH(aq);E=1.05VPbO2(s)+H2O(l)+2ePbO(s)+2OH(aq);E=+0.28VIO3(aq)+2H2O(l)+4eIO(aq)+4OH(aq);E=+0.56V

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a

+0.56

b

+0.28

c

+0.00

d

+0.74

answer is D.

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Detailed Solution

For spontaneous Eo > o ,
minimum possible spontaneous Eo = 0.28

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