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Q.

From the given sets of quantum numbers the one that is inconsistent with the theory is

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a

n = 3; l = 2; m = –3; s = +1/2

b

n = 4; l = 3; m = 3; s = +1/2

c

n = 2; l = 1; m = 0; s = –1/2

d

n = 4; l = 3; m = 2; s = +1/2

answer is A.

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Detailed Solution

For a particular n value, l values is from 0 to n−1.

For a particular l value,  m values are −l to +l

n =3, l =0,1,2

m =−2,−1,0,1,2

s =+12 or 12
But here, the value of m given is −3 which is not possible.

Hence, it is inconsistent with the theory.

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