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Q.

From the information given in the passage, what is the most likely configuration of the cobalt d-electrons for the species

 (A) CoCl63 and (B) CoNO263?

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a

both (A) and (B) have low spin

b

(A) has high spin; (B) has low spin

c

(A) has low spin; (B) has high spin

d

Both (A) and (B) have high spin

answer is B.

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Detailed Solution

Cl always behaves as weak field ligand so high spin complex formed. Also here o is not sufficient to overcome pairing energy P, NO2Θ with Co behaves as strong field ligand and hence low spin complex. Also  o > P and hence pairing takes place.

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