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Q.

Fusion of chromite ore (FeCr2O4) with  Na2CO3 in the presence of O2 gives X which on acidification with conc.H2SO4  gives Y. Both X and Y contain chromium ion. Correct statement(s) is/are:

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a

Both X and Y are colourful compound and colour of these compounds is due to ligand to metal charge transfer.

b

Both X and Y are paramagnetic in nature.

c

Acidified solution of Y can convert  Sn2+ ion into  Sn4+ ion.

d

Both X and Y have  Question Image bond

answer is C, A.

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Detailed Solution

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FeCr2O4+Na2CO3+O2Na2CrO4X+Fe2O3+CO2        Na2CrO4+H+Na2Cr2O7'Y'+H2O

Question Image 

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