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Q.

Gas A taken in a closed rigid container is allowed to decompose Partially according to the reaction. 

A(g)2B(g)+3C(g)

The gaseous mixture formed effuses 1.5 times faster than a gas having molecular weight 105 under similar conditions. Find the mole fraction of C in the gaseous mixture formed. 

Given:    Mol. wt.  of A=140

                Mol. wt.  of B=64

               Mol. wt.  of C=4

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answer is 5.

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Detailed Solution

A(g)2B(g)2a1-a  =3C(g)

1.5=105M

M=46.6746.67×(1+4α)=140×1α=0.5XC=3×0.51+4×0.5=0.5

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