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Q.

Gas phase decomposition of Di-tert-butyl peroxide (Me3COOCMe3) (DTBP) to acetone and ethane follows first order kinetics. The plot of log P vs time (t) is as given below. (P is pressure of DTBP in torr)

Me3COOCMe3(g)2MeCOMe(g)+C2H6(g)
 

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In one hour, the percentage dissociation of DTBP is found to be 'x' and the pressure of the system after one hour is found to be 'y' torr. 

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