Q.

Gaseous N2O4 dissociates into gaseous NO2 according to the reaction N2O4(g)2NO2(g). At 300 K and 1 atm pressure, the degree of dissociation of N2O4 is 0.2. If one mole of N2O4 gas is contained in a vessel, then the density of the equilibrium mixture is: 

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a

3.11 g/L

b

4.56 g/L

c

6.22 g/L

d

1.56 g/L

answer is A.

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Detailed Solution

PM=dRT1×92(1+0.2)=d×0.0821×300d=3.11g/L

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Gaseous N2O4 dissociates into gaseous NO2 according to the reaction N2O4(g)⇌2NO2(g). At 300 K and 1 atm pressure, the degree of dissociation of N2O4 is 0.2. If one mole of N2O4 gas is contained in a vessel, then the density of the equilibrium mixture is: