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Q.

Gases liberated when Cu and Zn react with dil. HNO3 separately

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a

NO2, N2O

b

NO, N2O

c

NO, NO2

d

N2O, NO2

answer is C.

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Detailed Solution

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Reaction of Copper (Cu) with Dilute HNO3:

Copper is less reactive than hydrogen and does not displace it from acids like HCl or H2SO4.

However, it reacts with dilute HNO3 because HNO3 is a strong oxidizing agent. The reaction produces nitric oxide (NO) as the gas.

3Cu + 8HNO3 → 3Cu(NO3)2 + 2NO + 4H2O

Gas liberated: NO (Nitric oxide)

Reaction of Zinc (Zn) with Dilute HNO3:

Zinc is more reactive than hydrogen and reacts with dilute HNO3 to produce nitrous oxide (N2O) as the gas.

4Zn + 10HNO3 → 4Zn(NO3)2 + N2O + 5H2O

Gas liberated: N2O (Nitrous oxide)

Answer:

The gases liberated are:

  • Copper (Cu): NO
  • Zinc (Zn): N2O

Correct Option: C) NO, N2O

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