Q.

Geraniol, a volatile organic compound, is a component of rose oil. The density of the vapour is 0.46gL1 at 257C and 100 mm Hg. The molar mass of geraniol is______g mol-1 (Nearest Integer)

 [Given : R=0.082L atm K1mol1 ] 

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answer is 152.

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Detailed Solution

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Assuming ideal behaviour P=dRTM
P=100760atm,T=257+273=530K
d = 0.46 gm/L
So M=0.46×0.082×530100×760
= 151.93 152

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