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Q.

Give reasons for the following:
(a) Red phosphorus is less reactive than white phosphorus.
(b) Electron gain enthalpies of halogens are largely negative.
(c) N2O5 is more acidic than N2O3 .

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Detailed Solution

(a) Red phosphorus is more stable than white phosphorus. White phosphorus has angular strain in the P4 molecule, which make it very unstable and highly reactive.
(b) The atoms have only one electron less than the noble gas configuration. Therefore, halogens have large Negative electron gain enthalpy.
(c) N2O5 is highly unstable because it is present in +5 oxidation state. This make N2O5 more acidic.

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