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Q.

Give the correct order of initials T or F for following statements. Use T if statement is true and F if it is false :
(I) The order of repulsion between different pair of electrons is lplp>lpbp>bpbp
(II) In general, as the number of lone pair of electrons on central atom increases, value of bond angle from normal bond angle also increases
(III)The number of lone pair on O in H2O is 2 while on N in NH3 is 1
(IV) The structures of xenon fluorides and xenon oxyfluorides could not be explained on the basis of VSEPR theory

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a

TTTF

b

TFTF

c

TFTT

d

TFFF

answer is B.

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Detailed Solution

(ii) (F) In general as the number of lone pair of electrons on central atom increases, value of bond angle from normal bond angle decreases due to lplp>lpb
(IV) (F) Structures of xenon fluorides and xenon oxy fluoride are explained on the basis of VSEPR theory.
In SOBr2, S-O bond has maximum bond length in comparison to S-O bond lengths in SOF2 and SOCl2, because in SOBr2, S-O bond has been formed by hybrid orbital containing less s-character.

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