Q.

Give the IUPAC name  of the following: CH3CH2CHO.


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a

Propan-1-al

b

Propan-1-ol

c

Prop-1-al

d

Pro-1-panal 

answer is A.

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Detailed Solution

Concept- The compounds with ‘CHO’ group are aldehydes and their name ends with ‘al’.
IUPAC rules for naming aldehydes are:
       The name of an aldehyde ends with “al”.
       Choose the longest carbon chain for the root name.
       Number the carbon atoms on this longest chain such that the carbon of -CHO the group gets the lowest number.
       Identify the other substituents and their position.
       If the same substituent appears more than once, then the prefix (di, tri, tetra) is used to indicate their frequency.
       If there are more than 2 substituents, they are named in alphabetical order with the position written ahead of them.
Thus, using the above rules, the given compound is named propan-1-al as ‘prop’ represents 3 carbon atoms.
Hence, the correct option is (1).
 
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