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Q.

Give the major product obtained when propene reacts with HBr

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a

2-bromo propane

b

1-bromo propene

c

1-bromo propane

d

2-bromo propene

answer is B.

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Detailed Solution

In presence of peroxide addition takes place according to Anti-Markownikoff’s rule and hydrogen atom goes to that carbon atom which is less hydrogenated.

CH3-CH=CH2+HBr→peroxideCH3-CH2-CH2-Br

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