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Q.

Given are the bond enthalpy data: εCC=374kJmol1; εC=C=632kJmol1; εCH=411kJmol1 If the enthalpy formation of benzene from gaseous atoms is 5536 kJ mol-1 the resonance energy benzene is

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a

-52 kJ mol-1

b

-62 kJ mol-1

c

-72 kJ mol-1

d

-82 kJ mol-1

answer is A.

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Detailed Solution

Enthalpy of formation of benzene from the gaseous atoms using bond enthalpies data is ΔH=3εCC3εC=C6εCH=[3(374)3(632)6(411)]kJmol1=5484kJmol1Resonance energy=ΔH( actual )ΔH f(from bond enthalpy)= (-5536 + 5484) kJ mol-1 = -52 kJ mol-1 

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