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Q.

Given are the following informations at 298 K.

    N2O4(g)2NO2(g)ΔfH/kJmol1    9.16    33.18ΔfG/kJmol1    97.54    51.31

The reaction is carried out in a closed vessel starting from N2O4.

The standard equilibrium constant Kp at 298 K is

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a

0.29

b

 0.129

c

2.43

d

5.67

answer is B.

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Detailed Solution

Kp=expΔfG/RT =exp5.08×103Jmol1/8.314JK1mol1(298K) =exp(2.05)=0.129

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Given are the following informations at 298 K.    N2O4(g)⇌2NO2(g)ΔfH∘/kJmol−1    9.16    33.18ΔfG∘/kJmol−1    97.54    51.31The reaction is carried out in a closed vessel starting from N2O4.The standard equilibrium constant Kp∘ at 298 K is