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Q.

Given are the reduction potentials:

MnO4+8H++5eMn2++4H2O    E12CO2+2H++2eHOOCCOOH    E2

The cell potential, having oxidation of oxalic acid with KMnO4 as the cell reaction, will be 

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a

Ecell=5E25E1

b

Ecell =5E12E2

c

Ecell =E1E2

d

Ecell =E2E1

answer is A.

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Detailed Solution

The half-cell reactions will be.

MnO4+8H++5eMn2++4H2O;      Reduction, right-hand electrode

HOOCCOOH2CO2+2H++2e¯;       Oxidation, left-hand electrode

The cell potential, having oxidation of oxalic acid with KMnO4 as the cell reaction, will be Ecell =EREL=E1E2

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