Q.

Given below are 2 conductometric titration plots. In each plot conductance of a solution in flask is plotted on x-axis (shown as a) and the volume of the titrant added from burette is plotted on y-axis (shown as b). Which of the following option(s) is/are correct ?

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a

Plot 1 corresponds to titration of NaOH (in flask) versus mixed acid HCl + CH3COOH
(in burette)

b

Plot 2 corresponds to titration of NaOH (in flask) versus mixed acid HCl + CH3COOH
(in burette)

c

Plot 1 corresponds to titration of NaOH (in flask) versus HCl (in burette)

d

Plot 2 corresponds to titration of NaOH (in flask) versus HCl (in burette)

answer is A, C.

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Detailed Solution

For titration of HCl v/s NaOH, conductance first decreases and then increases.
For titration of mixed acid HCl + CH3COOH v/s NaOH, also, conductance first decreases and then increases.

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