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Q.

Given below are half cell reactions 
MnO4+8H++5e  Mn2++4H2O  ;      EMnO4/Mn+2o=1.510V
12O2+2H++2eH2O;                         EO2/H2OO=1.223V
will the permanganate ion liberate O2 from water in the presence of an acid?

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a

No, because Eo cell = - 0.287 V

b

Yes, because Eo cell = + 0.287 V

c

Yes, because Eo cell = + 2.733 V

d

No, because Eo cell = - 2.733 V

answer is D.

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Detailed Solution

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E0cell=R.pofcathodeR.Pofanode
=1.5011.223=+0.287v
Since E0cell is positive, the cell reaction is feasible.

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