Q.

Given below are some nitrogen containing compounds.
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Each of them is treated with HCl separately. 1.0 g of the most basic compound will consume ______mg of HCl.
(Given molar mass in g mol–1 C:12, H : 1, O : 16, Cl : 35.5)

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answer is 341.

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Detailed Solution

Benzyl Amine is most basic due to localised lone pair.

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Mole of benzyl Amine 1107=0.00934mole

1 Mole of Benzyl amine consumed 1 mole of HCl
So, Mole of HCl consumed → 0.00934 mole
Mass of HCl consumed → 0.00934 × molar mass of HCl
= 0.00934 × 36.5
= 0.341 gm
= 341 mg

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