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Q.

Given below are the half-cell reactions, 
         Mn2++2eMn;E=1.18eV2Mn3++eMn2+;E=+1.51eV
The E for 3Mn2+Mn+2Mn3+ will be 

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a

-2.69 V, the reaction will not occur

b

-2.69 V, the reaction will occur

c

-0.33 V, the reaction will not occur

d

-0.33 V, the reaction will occur

answer is A.

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Detailed Solution

If Ecello is positive, reaction is spontaneous, otherwise it is non-spontaneous.
                 Mn2++2eMn;E=1.18V         2Mn2+2Mn3++2e;E=1.51V         3Mn2+Mn+2Mn+3                E=Eoxi+Ered=1.51+(1.18)=2.69V
Negative Ecello of the reaction indicates that reaction is non-spontaneous.

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