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Q.

Given below are two statements : one is labeled as Assertion A and the other is labeled as Reason R.
Assertion (A) : In TlI3 isomorphous to Csl3, the metal is present in +1 oxidation state.
Reason (R) : Tl metal has Thirteen f - electrons is its electronic configuration.
In the light of the above statements, choose the most appropriate answer from the options given below.

 

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a

Assertion is not correct but reason is correct.

b

Both Assertion and reason are correct but reason is not the correct explanation of assertion.

c

Assertion is correct but reason is not correct.

d

Both assertion and reason are correct and reason is the correct explanation of assertion.

answer is A.

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Detailed Solution

TIl3Tl+ and I3-;    Csl3Cs+ and  I3-
Both have same crystalline structures.
So TlI3 and Csl3 are isomorphous.
Electronic configuration of Tl=Xe 4f14 5d106s26p1

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