Q.

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R). 
Assertion (A) : Experimental reaction of CH3Cl with aniline and anhydrous AlCl3 does not give o and p-methylaniline.
Reason (R) : The -NH2 group of aniline becomes deactivating because of salt formation with anhydrous AlCI3 and hence yields m-methyl aniline as the product. 

In the light of the above statements, choose the most appropriate answer from the options given below:

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a

Both (A) and (R) are true and (R) is the correct explanation of (A).

b

(A) is true, but (R) is false.

c

(A) is false, but (R) is true.

d

Both (A) and (R) are true but (R) is not the correct explanation of (A).

answer is C.

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Detailed Solution

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AICI3 being a Lewis acid reacts with -NH2 group of aniline resulting in salt formation which acts as a strong electron withdrawing group. Hence, it does not give reaction.

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