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Q.

Given below are two statements: One is labeled as Assertion (A) and the other is labeled as Reason (R).

Assertion (A): Permanganate titrations are not performed in presence of hydrochloric acid.
Reason (R): Chlorine is formed as a consequence of oxidation of hydrochloric acid.
In the light of the above statements choose the correct answer from the options given below.

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a

Both A and R are correct and R is the correct explanation of A

b

Both A and R are correct but R is not the correct explanation of A.

c

A is correct but R is not correct.

d

A is not correct but R is correct.

answer is A.

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Detailed Solution

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Hydrochloric Acid(HCl) is usually not used in the process of titration because it reacts with the indicator potassium permanganate KMnO4 used in the process. It reacts with KMnO4 solution and gets oxidized resulting in the liberation of chlorine gas.

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