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Q.

Given below are two statements, one is labeled as Assertion (A) and reason (R).

Assertion (A) : When Na2CO3 is treated against HCl in presence of phenolphthalein indicator, it is converted to NaCl. 

Reason (R) : Phenolphthalein shows colour change in the pH range of (3.54.6).

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a

if both (A) and (R) are true but (R) is not the correct explanation of (A).

b

if (A) is true but (R) is false

c

if both (A) and (R) are true and (R) is the correct explanation of (A).

d

if both (A) and (R) are false

answer is C.

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Detailed Solution

When Na2CO3​ reacts with HCl, the compound is neutralized in a step-wise manner, that is, NaHCO3​ is formed first before they are completely transformed to H2CO3 (or CO2+H2O).

Na2CO3+HClNaHCO3+NaCl..........(I)   NaHCO3+HClH2CO3 +NaCl............(II)

In the presence of Phenolphthalein (ph) indicator, it only shows the(I) reaction. 

Phenolphthalein shows the colour change at pH 8.2 to 10.

 

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