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Q.

Given below are two statements. One is labelled as Assertion (A) and the other is labelled as reason (R). 

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An Intiative by Sri Chaitanya

a

Both (A) and (R) are true but (R) is not the correct explanation of (A)

b

Both (A) and (R) are true and (R) is the correct explanation of (A)

c

Both (A) and (R) are false

d

(A) is true but (R) is false

answer is B.

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Detailed Solution

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when benzaldehyde condenses with malonic acid in presence of pyridine as a basic catalyst. Here malonic acid and the base present generate a carbanion which acts as a nucleophile and attacks on the benzaldehyde.

The aldehyde group (-CHO) in benzaldehyde is a meta-director as it is an electron-withdrawing in nature. Aldehyde shows -R effect and in its resonance

 

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