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Q.

 Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason  .
Assertion A :  [CoCl(NH3)5]2+absorbs at lower wavelength of light with respect to [Co(NH3)5(H2O)]3+
Reason : It is because the wavelength of the light absorbed depends on the oxidation state of the metal ion.
In the light of the above statements, choose the correct answer from the options given below:
 

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a

Both A and R are true and   is the correct explanation of A

b

A is false but R is true

c

A is true but R is false

d

Both A and R are true but R is NOT the correct explanation of A

answer is D.

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Detailed Solution

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[COCl(NH3)5]2absorbs at higher wavelength light with respect to [CO(NH3)5(H2O)]3is due to ligand strength {ligand strength order Cl<H2O}
(or) same metal and same oxidation state depends on ligand strength 
 

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