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Q.

Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R:
Assertion A: Equilibrium constant increases with increase in temperature for an endothermic reaction.
Reason R: For an endothermic reversible reaction, with increase in temperature, kf  decreases while kb  increases.
In the light of the above statements, choose the most appropriate answer from the options given below:

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a

Both A and R are correct and R is the correct explanation of A
 

b

Both A and R are correct but R is NOT the correct explanation of A
 

c

A is not correct but R is correct
 

d

A is correct but R is not correct

answer is D.

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Detailed Solution

Assertion is true, if ΔH=+ve  
Tkeq .
Reason is wrong, kc=kfkb ,  kf and kb  always increase with increase  in temperature.   in kf  less than   in  kb

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