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Q.

Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R:
Assertion-(A): Phenol is less acidic than acetic acid in aqueous solution.
Reason-(R): Phenoxide ion is more stable than alkoxide ion.
In light of the above statements, choose the most appropriate answer from the options given below:

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a

'A' is true and 'R' is false

b

Both 'A' and 'R' are true and 'R' is the correct explanation of 'A'.

c

Both 'A' and 'R' are true and 'R' is not the correct explanation of 'A'.

d

A is false, but R is true

answer is B.

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Detailed Solution

As phenoxide ion is resonance stabilized, it is more stable than alkoxide ion so phenol has more tendency of losing  H+  so it is more acidic than alcohol.

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