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Q.

Given below are two statements. One is labelled as Assertion A and the other is labelled as Reason R.

Assertion A: The first ionization enthalpy for oxygen is lower than that of nitrogen.

Reason R: The four electrons in 2p orbitals of oxygen experience more electron-electron repulsion.

In the light of the above statements, choose the correct answer from the options given below.

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a

Both A and R are correct and R is the correct explanation of A.

b

Both A and R are correct and R is not the correct explanation of A.

c

A is correct but R is not correct.

d

A is not correct but R is correct

answer is A.

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Detailed Solution

N-atom has a half-filled p-sub shell which provides it extra stability, O-atom on the other hand has four electrons in the p-subshell , causing greater electron-electron repulsion and lesser stability. 

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