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Q.

Given below are two statements. One is labelled Assertion (A) and the other is labelled Reason (R). 

Assertion (A) : KCN reacts with methyl chloride to give major product as  methyl isocyanide

Reason  (R) : CN is a weak nucleophile.

In light of the above statements, choose the correct answer from the options given below.

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a

If both (A) and (R) are true and (R) is not the correct explanation of (A) 

 

b

If both (A) and (R) are false

c

If both (A) and (R) are true and (R) is the correct explanation of (A) 

 

d

If (A) is true but (R) is false 

 

answer is D.

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Detailed Solution

Assertion is wrong but reason is correct statement.
Correct Assertion KCN reacts with methyl chloride to give the mixture of methyl cyanide and methyl isocyanide in which methyl cyanide predominates because of stable CC bond in methyl cyanide

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