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Q.

Given below are two statements:
Statement I: Controlled nitration of aniline can be done conveniently by protecting   group through acetylation.
Statement II: Direct nitration of aniline yields ortho, meta and para derivatives.
In the light of above statements, choose the most appropriate answer from the options given below: 

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a

Statement – I is true and statement – II is false

b

Both statement - I & II are true

c

Both statement – I & II are false

d

Statement – I is false and statement II is true 

answer is A.

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Detailed Solution

Direct nitration of aniline yields 2%ortho, 48%meta and 51%para derivatives.

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