Q.

Given below are two statements :
Statement-I : The conversion proceeds well in the less polar medium.
CH3CH2CH2CH2ClHO CH3CH2CH2CH2OH+Cl
Statement-II : The conversion proceeds well in the more polar medium.

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In the light of the above statements, choose the correct answer from the options given below.

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a

Statement I is true but statement II is false

b

Both statement I and statement II are false

c

Both statement I and statement II are true

d

Statement I is false but statement II is true

answer is A.

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Detailed Solution

CH3CH2CH2CH2Cl+OH Reactant (higher charge density)

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Transition state (less charge density)
 This reaction will proceed faster in less polar medium which will not increase the activation energy value.

CH3CH2CH2CH2Cl+R3N Reactant (low charge density)

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Transition state (Higher charge density)

 This reaction will proceed faster in more polar medium which will decrease the activation energy value.

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