Q.

 

Given below are two statements:
Statement 1: The identification of Ni2+ is carried out by dimethyl glyoxime in the presence of NH4OH

Statement 2: The dmg is a bidentate neutral ligand.

 In the light of the above statements, choose the correct answer from the options given below 

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a

Both statement 1 and statement II are true

b

Statement I is true but statement II is false

c

Both Statement I and statement II are false

d

Statement I is false but statement II is true

answer is D.

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Detailed Solution

The ligand dimethyl glyoxime is neutral and has no effect. In the presence of NH4OH, Ni2+ reacts with dimethyl glyoxime to form dimethyl glyoximate, which then forms rosy red ppt.

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Dimethylglyoxime is a -negative bidentate legend

 

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 Given below are two statements:Statement 1: The identification of Ni2+ is carried out by dimethyl glyoxime in the presence of NH4OHStatement 2: The dmg is a bidentate neutral ligand. In the light of the above statements, choose the correct answer from the options given below