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Q.

Given below are two statements:
Statement I : The boiling points of aldehydes and ketones are higher than hydrocarbons of comparable molecular masses because of weak molecular association in aldehydes and ketones due to dipole - dipole interactions. 
Statement II : The boiling points of aldehydes and ketones are lower than the alcohols of similar molecular masses due to the absence of H-bonding 
In the light of the above statements, choose the most appropriate answer from the options given below:

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a

Statement I is correct but statement II is incorrect

b

Both Statement I and Statement II are correct

c

Statement I is incorrect but statement II is correct

d

Both statement I and Statement II are incorrect

answer is D.

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Detailed Solution

Carbonyl compounds of comparable molar mass do not show hydrogen bonding, hence boiling point is lesser than alcohols.

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