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Q.

Given below are two statements
Statement –I : [Ni(Cl)4]2 is tetrahydral & diamagnetic Complex with dsp2 hybridization for Ni, but [Ni(CN)4]2  is square planar, paramagnetic complex with dsp2 hybridization for Ni, but [Ni(CO)4 ] is tetrahydral & diamagnetic complex with dsp2 hybridization for Ni
Statement –II :  [NiCl4]2,[Ni(CO)4],[Ni(CN)4]2 have same d-electron configuration  have same geometry  and are paramagnetic.

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a

Both statement I & statement II are false.

b

Statement I is incorrect but statement II is true. 

c

Statement I is correct but statement II is false.

d

Both statement I & statement II are true

answer is A.

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Detailed Solution

[Ni(Cl)4]2  is tetrahydral & paramagnetic Complex with sp3 hybridization 
[Ni(CN)4] 2  is square planar, diamagnetic complex with dsp2 hybridization
[Ni(CO)4 ] is tetrahydral & diamagnetic complex with sp3

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