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Given below are two statements:
Statement I: Potassium permanganate on heating at 573 K forms potassium manganate.
Statement II: Both potassium permanganate and potassium manganate are tetrahedral and paramagnetic in nature.
In the light of the above statements, choose the most appropriate answer from the options given below:

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Both statement I and statement II are true

Statement I is true but statement II is false

Statement I is false but statement II is true

Both statement I and statement II are false

answer is B.

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Detailed Solution

$2 K M n O_{4} \overset{513 K (minimum temperature)}{\to} K_{2} M n O_{4} + M n O_{2} + O_{2}$

$M n O_{4}^{- 2} \to$ Paramagnetic

$M n O_{4}^{-} \to$ Diamagnetic

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