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Q.

Given below are two statements:
Statement I: The E0 value for  Ce 4+/Ce3+is+1.74V.
Statement II: Ce is more stable in Ce 4+ state than Ce3+ state.
In the light of the above statements, chose the most appropriate answer from the options given below:

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a

Both statement I and statement II are correct

b

Statement I is incorrect but statement II is correct

c

Both statement I and statement II are incorrect

d

Statement I is correct but statement II is incorrect

answer is D.

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Detailed Solution

Statement I is correct as +3 oxidation state of lanthanoids is more stable. Thus ECe4+/Ce+30 is positive.Statement II is incorrect as lanthanoids are more stable in +3 oxidation state.

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