Q.

Given is the following information: H2SO4(l)+5H2O(l)H2SO45H2O(l): Δ1H=58.0kJmol1 A solution of specific heat capacity 4.184 J K-1g-1  is obtained when 1 mol of H2 SO4 is added to 5 mol of H2O. The temperature change in the above process will be about

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a

154.0 °C

b

98.0 °C

c

73.76 °C

d

54.2 °C

answer is C.

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Detailed Solution

We will have mcpΔT=ΔfH 

Wherem=mH2SO4+mH2O=(nM)H2SO4+(nM)water =1.0mol298gmol1+(5.0mol)18gmol1=188gWhere ΔT=ΔfHmcp=58×103J(188g)4.184JC1g1=73.74C

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