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Q.

Given : Radius of A2+ = 100 pm; Radius of C+ = 240 pm; Radius of B2- = 300 pm; Radius of D- = 480 pm. Which is / are correct statement?

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a

 Coordination number of A2+ in comp AB is 4

b

 Coordination number of A2+ in comp AB is 6

c

 Coordination number of C+in comp CD is 6

d

 Coordination number of C+in comp CD is 8

answer is A.

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Detailed Solution

rA2+rB2=100300=0.333 rC+rD=240480=0.5

B2 are at F.C.CD at F.C.C.latticepoint 

and A2+ ion are C+ in all octahedral voids alternate tetrahedral void

C.No. of AB = 4 : 4          C.No. of CD = 6 : 6

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